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Three-coordinate binuclear copper(I) complex: model compound for the copper sites in deoxyhemocyanin and deoxytyrosinase

✍ Scribed by Karlin, Kenneth D.; Gultneh, Yilma; Hutchinson, John P.; Zubieta, Jon

Book ID: 126861364
Publisher: American Chemical Society
Year: 1982
Tongue: English
Weight: 421 KB
Volume: 104
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00383a047

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## Abstract Five small, completely protected, L‐histidyl(N^__τ__^Bzl)‐containing peptides, were synthesized and characterized by NMR spectroscopy, i.e., R‐Ala‐His(N^τ^‐Bzl)‐Ala‐R′ (1), R‐His(N^__τ__^‐Bzl)‐Ala‐Ala‐Ala‐Met‐R′ (2), R‐His(N^__τ__^‐Bzl)‐Ala‐Ala‐Ala‐His(N^__τ__^‐Bzl)‐R′ (3), R‐His(N^__τ_