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Three-Component Reactions with Aryl Isothiocyanates. Synthesis of 5-Arylimino-1,2,4-thiadiazolidin-3-ones

✍ Scribed by Prof. Dr. Gerrit L'abbé; Gabriël Verhelst


Publisher
John Wiley and Sons
Year
1976
Tongue
English
Weight
219 KB
Volume
15
Category
Article
ISSN
0044-8249

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On the Mechanism of the Reactions of 4-A
✍ Gerrit L'abbé; Ernestine Albrecht 📂 Article 📅 2010 🏛 Wiley (John Wiley & Sons) ⚖ 108 KB

Although the first cycloaddition-elimination reactions of 4-alkyl-5-arylimino-1,2,3,4-thiatriazolines (1) with heterocumulenes were reported in 1976-78,' insight into the mechanistic puzzle has been gained recently, and then only for isothiocyanates.2 For isocyanates, which furnish l ,2,4-thiadiazol