Three-center bonds in electron-deficient compounds. Localized molecular orbital approach
โ Scribed by Lipscomb, William N.
- Book ID
- 120430696
- Publisher
- American Chemical Society
- Year
- 1973
- Tongue
- English
- Weight
- 581 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0001-4842
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract Hypervalent bond (three centerโfour electron bond: 3cโ4e) is the central feature of the structure and reactivity of hypervalent compounds. The S๏ฃฟS๏ฃฟS bond of thiathiophthene, the soโcalled noโbond resonance compound, is realized as one of the examples of 3cโ4e bond centered at the sulfur
using the group symmetrical localized molecular orbitals (SLhfOs) as configuration-generating orbitals (CGOs) of many-electron wave functions, the symmetry adaptation of many-electron spaces is greatly simplified, and novel orthogonal bonded functions (OBFs), as complete space-and spin-adapted antis