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Three-body nonadditive effects for hydrogen bonded water molecules: SCF study of hydrated species including H2S and various metal ions

✍ Scribed by O. Novaro


Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
673 KB
Volume
23
Category
Article
ISSN
0020-7608

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✦ Synopsis


Abstract

The relative importance of purely nonadditive three‐body terms in solvated systems is assessed through ab initio LCAO–MO–SCF studies of hydrogen bonded structures containing two or more water molecules plus a solvate species. Among the latter the cases of Li^+^, Ca^2+^, and Mg^2+^ ions (of biological interest for aminoacid release processes in membrane transport) and of HDS molecules (of industrial importance in processes for the production of heavy water) are studied.