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Three- and four-coordinated silver(I) ions in the coordination polymers [Ag(Me4Pyz)2]PF6and [Ag(2,3-Et2Pyz)2]PF6

✍ Scribed by Yu. V. Kokunov; Yu. E. Gorbunova; V. V. Kovalev

Book ID: 110182735
Publisher: SP MAIK Nauka/Interperiodica
Year: 2010
Tongue: English
Weight: 324 KB
Volume: 55
Category: Article
ISSN: 0036-0236
DOI: 10.1134/s0036023610100104

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## Abstract Two prototypical carbido anionic clusters, the prismatic [Rh~6~C(CO)~15~]^2–^ and the octahedral [Ru~6~C(CO)~16~]^2–^, can add two electrophilic Ag–NCMe^+^ fragments, which were exploited to condense the clusters with bifunctional heterocyclic ligands, such as pyrazine (pyz) or 4,4′‐bip