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Thorpe–Ingold Effect on the Helicity of Chiral Alternating Silylene-Divinylarene Copolymers

✍ Scribed by Mei-Yu Yeh; Tien-Yau Luh


Book ID
112005519
Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
293 KB
Volume
3
Category
Article
ISSN
1861-4728

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## Abstract ATRP‐induced cyclopolymerization of dialkylsilylene‐tethered bismethacrylates leads to the corresponding polymethacrylate having fourteen‐membered cyclic pendants. The presence of bulky substituents on silicon is essential to facilitate the overall cyclopolymerization process in **3**.