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Thorium-EDTA complexes—A conductometric study

✍ Scribed by V.T. Athavale; S.C. Saraiya; A.K. Sundaram


Publisher
Elsevier Science
Year
1960
Tongue
English
Weight
95 KB
Volume
23
Category
Article
ISSN
0003-2670

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✦ Synopsis


Discussion

Chloroform recovered by the proposed method was suitable for analytical purposes; there was no change in the optical densities of dithizone solutions prepared from it after 5 days storage in the dark at ,,, 5 ~ A batch of dithizone residues contaminated with phosgene gave a satisfactory product when purified by the proposed method. The time taken for the proposed method was approximately 2 hours as against 5 hours for that of MULLIN AND RILEY. Although the proposed method has only been applied to residues containing lead and zinc dithizonates, it should be applicable to other dithizonates provided they are easily dissociated and contain metals which react with EDTA.


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Conductometric and Potentiometric Study
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## Abstract The interaction between sodium succinate and thorium chloride solutions in presence of glucose solutions of suitable concentrations has been investigated adopting conductometric and potentiometric titration methods. The experimental data shows the formation of the normal disuccinate, Th