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Thiyl radicals studied by muon level-crossing spectroscopy

✍ Scribed by Mary V. Barnabas; David C. Walker

Publisher: Elsevier Science
Year: 1990
Tongue: English
Weight: 369 KB
Volume: 168
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(90)85093-r

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✦ Synopsis

Addition of muonium atoms to thiocarbonyl compounds is shown to result in the formation of sulfur-centered radicals (R-s; which are observed by level-crossing-resonance spectroscopy. This technique enables one to determine the proton and nitrogen hyperfine coupling constants in thiyl radicals: a task which cannot be accomplished directly be ESR. The radicals are formed here in dilute aqueous solution from muonium atoms produced by irradiation with positive muons.

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