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Third-order nonlinear optical properties of in-backbone substituted conjugated polymers

✍ Scribed by Gubler, U.; Concilio, S.; Bosshard, Ch.; Biaggio, I.; Günter, P.; Martin, R. E.; Edelmann, M. J.; Wytko, J. A.; Diederich, F.


Book ID
121385603
Publisher
American Institute of Physics
Year
2002
Tongue
English
Weight
220 KB
Volume
81
Category
Article
ISSN
0003-6951

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Third-order nonlinear optical properties
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The thirdarder microscopic hyperpolarizability y is calculated for finite bridged polymers of the form A-B-A-B-... using simple model Hamiltonians. Generally, the even-and odd-numbered chains show markedly different behavior, with the addition or subtraction of one chain unit resulting in a predicte