✦ LIBER ✦

Third-order non-linear optical properties of one-dimensional metal complexes

✍ Scribed by T. Kamata; T. Fukaya; M. Mizuno; H. Matsuda; F. Mizukami

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 422 KB
Volume: 221
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(94)00268-1

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✦ Synopsis

The third-order non-linear optical properties of evaporated thin films of d* transition metal complexes with dionedioxime have been estimated by third harmonic generation. They formed one-dimensional structures and showed large optical nonlinearities. Resonance effects were observed for respective metal complexes. The maximum xc3) value of 5.6~ lo-" esu was obtained at the near three-photon resonance wavelength for the platinum complex. The delocalized electrons in linear metal chains may be essential for exhibiting large non-linear optical effects.

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