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Third-body-assisted, binary ion—molecule reactions. The reaction NH+3 + H2 → NH+4 + H

✍ Scribed by H. Böhringer

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
392 KB
Volume
122
Category
Article
ISSN
0009-2614

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✦ Synopsis

AH was stud& m a selected-ion dnft tube as a funcfion of gas density and temperature from 2U to 298 K A pressure dependence of the second-order rate coefficient was observed which indicates Hal Lhe reactlon rate is Increased when the intermedlate complexes colhde with a third body. It IS concluded that one has to be aware In general that a reacllon Lhat IS found to be slow at low or moderate density can be slgmficantly faster m a h&-pressure environment.

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