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Thiosubstituted Organophosphinic Acids as Selective Extractants for Mercury(II) from Acidic Chloride Solutions

✍ Scribed by Francis, T.; Reddy, M. L. P.

Book ID
121483588
Publisher
Taylor and Francis Group
Year
2003
Tongue
English
Weight
249 KB
Volume
21
Category
Article
ISSN
0736-6299

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Solvent extraction of zirconium(IV) from
Solvent extraction of zirconium(IV) from acidic chloride solutions using the thiosubstituted organophosphorus acids Cyanex 301 and 302
✍ B Ramachandra Reddy; J Rajesh Kumar; A Varada Reddy πŸ“‚ Article πŸ“… 2004 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 145 KB πŸ‘ 1 views

## Abstract Solvent extraction of zirconium(IV) from acidic chloride solutions has been carried out with the thiosubstituted organophosphorus acids Cyanex 301 and Cyanex 302. The extraction follows an ion exchange mechanism: MO^2+^~(aq)~ + 2 HA~(org)~ ↔ MOA~2(org)~ + 2 H^+^~(aq)~, where, M = Zr(IV)