Thiophene-based dendronized macromonomers and polymers
✍ Scribed by Prashant Sonar; Hadjar Benmansour; Thomas Geiger; A. Dieter Schlüter
- Book ID
- 108249651
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 407 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0032-3861
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## Abstract Radical polymerizations from third to fifth generation macromonomers were conducted in supercritical carbon dioxide (scCO~2~). It was found that all monomers were not soluble in such a medium, and reactions occurred in the CO~2~‐swollen monomer matrices. Despite the expected severe diff
## Abstract **Summary:** Linear polymeric core, polyethylenimine (PEI), is successfully dendronized divergently using different‐generation polyamidoamine (PAMAM)‐type dendrons. The formed dendronized polymers are further end‐capped using long alkyl acrylate, hexyl acrylate, to give macromolecular a