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Thiophene adsorption and decomposition on clean and sulfur precovered Ru(0001)

✍ Scribed by R.A. Cocco; B.J. Tatarchuk


Publisher
Elsevier Science
Year
1989
Weight
63 KB
Volume
218
Category
Article
ISSN
0167-2584

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There is no bonding between Au and S atoms coadsorbed on top of Ru (000 1) . Au compresses S into small islands of high local coverage, causing dramatic changes in the kinetics of sulfur desorption. The compression reduces the adsorption energy of sulfur on Ru(0001 ), favoring the desorption of Sz i