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Thiols in Ugi- and Passerini–Smiles-Type Couplings

✍ Scribed by Anaëlle Barthelon; Laurent El Kaïm; Marie Gizolme; Laurence Grimaud

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
421 KB
Volume
2008
Category
Article
ISSN
1434-193X

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✦ Synopsis

Abstract

The use of the Smiles rearrangement in Ugi‐type couplings with aromatic mercaptans allows for the straightforward, multicomponent formation of α‐arylamino thiocarboxamides. The scope of this new four‐component coupling is further broadened with the use of heterocyclic mercapto derivatives that afford thioamides of high biological interest in one step. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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