𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Thiol as a Synthon for Preparing Thiocarbonyl: Aerobic Oxidation of Thiols for the Synthesis of Thioamides

✍ Scribed by Wang, Xi; Ji, Miran; Lim, Seungyeon; Jang, Hye-Young

Book ID
125538839
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
345 KB
Volume
79
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Straightforward and Diastereoselective S
Straightforward and Diastereoselective Synthesis of Tetrafunctionalized Thiol Synthons for the Design of Metallopeptidase Inhibitors
✍ Christelle David; Laurent Bischoff; Bernard P Roques; Marie-Claude FourniΓ©-Zalus πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 125 KB

Tetrafunctionalized thiol-containing synthons with different side-chains have been prepared with good yields by a straightforward diastereoselective and general methodology. The key step of the synthesis consisted of a tandem reduction and Wittig-Horner reaction, which conserved the stereochemistry

9-(4-Methoxyphenyl)xanthen-9-thiol: A us
9-(4-Methoxyphenyl)xanthen-9-thiol: A useful reagent for the preparation of thiols
✍ Jonathan H. Marriott; Mina Mottahedeh; Colin B. Reese πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 252 KB

Treatment of 5'-chloro-S'-deoxynucleosides (2) with the conjugate base of 9-(4methoxyphenyl)xanthen-9-thiol (3b), followed by acid-promoted removal of the S'-S-[g-(4methoxyphenyl)xanthen-9-yl] group in the presence of pyrrole gives the corresponding 5'deoxy-5'-mercaptonucleosides (1) in good yields.