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Thioether, Dinitrogen, and Olefin Complexes of (PNP)Rh: Kinetics and Thermodynamics of Exchange and Oxidative Addition Reactions

✍ Scribed by Gatard, Sylvain; Guo, Chengyun; Foxman, Bruce M.; Ozerov, Oleg V.


Book ID
125833564
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
227 KB
Volume
26
Category
Article
ISSN
0276-7333

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Oxidative Addition Reactions of Organorh
✍ Christine Hahn; Michael Spiegler; Eberhardt Herdtweck; Rudolf Taube πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 261 KB πŸ‘ 3 views

As part of studies aimed at delineating the mechanism of the rhodium(III) complexes 2a,b and 3a,b have been characterized by 31 P-, 1 H-, and 13 C-NMR spectrometry, as rhodium complex-catalyzed hydroamination of olefins, the model complexes [Rh(PNP)R] (R = CH 3 1a, C 6 H 5 1b) have well as by EI mas