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Thiocyante-catalyzed cis-trans isomerization of cis-.beta.-acetylacrylic acid. A model for maleylacetoacetic acid

✍ Scribed by Stevens, Kenneth D.; Seltzer, Stanley

Book ID: 127287895
Publisher: American Chemical Society
Year: 1968
Tongue: English
Weight: 865 KB
Volume: 33
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo01274a049

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## Abstract __Cis__‐ and __trans__‐2,5‐diallyloxy‐2,5‐dihydrofuran have been prepared by acid catalyzed transacetalization of 2,5‐dimethoxy‐2,5‐dihydrofuran with allyl alcohol. As a by‐product, 1,1,3‐triallyloxypropane was formed from 2‐allyloxy‐2,5‐dihydrofuran intermediates. The __cis/trans__ con