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Thiocarbonyl Photochemistry: The Photoreactions of Pyrimidine-2-thione Derivative with Alkynes and Alkenes

โœ Scribed by Mohamed, Nadia Ragab; El-Saidi, Manal M. T.; Ali, Yasser Mahmoud; Nada, Afaf A.


Book ID
121457968
Publisher
Taylor and Francis Group
Year
2007
Tongue
English
Weight
181 KB
Volume
182
Category
Article
ISSN
1042-6507

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The photochemical synthesis of indole derivatives starting from the indoline-2-thiones 1 is described. Irradiation of indoline-2-thiones 1 in the presence of alkenes 3 gave 2-alkyl-3H-indoles 4-7 or 2-alkylindoles 8-22 through the ring cleavage of the intermediates, spirocyclic amino-thietanes, init