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Thiocarbonyl Compounds in [4+2] Cycloadditions: Preparative Aspects

✍ Scribed by Josef Breu; Peter Höcht; Uwe Rohr; Jürgen Schatz; Jürgen Sauer


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
234 KB
Volume
1998
Category
Article
ISSN
1434-193X

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✦ Synopsis


Cycloadditions of thiobenzophenones 1a and thio-structure especially the regiochemistry of the cycloadditions involved 1 H-and 13 C-NMR spectroscopy, and single-crystal fluorenones 2 with cyclic and open-chain dienes gave cycloadducts in high yields. Assignment of the product structure determination.


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Thio- and Selenocarbonyl Compounds as “S
✍ Uwe Rohr; Jürgen Schatz; Jürgen Sauer 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 210 KB

Normal, neutral, and inverse-type Diels-Alder reactions can Extensive kinetic studies prove the highly dienophilic activity of the C=S and C=Se double bond. Studies of the be observed in [4+2] cycloadditions of thio-and selenocarbonyl compounds 1-9 with various cyclic and aryl-, solvent and temperat