In the presence of a strong Lewis base, such as Et 3 N, trithio-1,8-naphthalic anhydride ( 3) is easily oxidized. Two improved syntheses of trithio-1,8naphthalic anhydride (3) are described. Trithio-1,8-naphthalic anhydride (3) undergoes Diels-Alder reactions with electron-deficient alkenes to give
β¦ LIBER β¦
Thioanhydrides. 3. Synthesis, properties and Diels-Alder reactions of sulfur analogs of 1,8-naphthalic anhydride
β Scribed by Lakshmikantham, M. V.; Chen, Wha; Cava, Michael P.
- Book ID
- 120077269
- Publisher
- American Chemical Society
- Year
- 1989
- Tongue
- English
- Weight
- 659 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0022-3263
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The stereoselectivities of the title reactions have been investigated from 140-340Β°C, and relative activation parameters for & and tm product formation have been determined.