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Thioamidoalkylation of 1,3-Dicarbonyl Compounds, Enol Silyl Ethers, and Enamines.

โœ Scribed by Alan R. Katritzky; Ilhami Celik; Ashraf A. A. Abdel-Fattah


Publisher
John Wiley and Sons
Year
2007
Weight
40 KB
Volume
38
Category
Article
ISSN
0931-7597

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O-silylated enolate phenylthioalkylation
โœ Hassan A. Khan; Ian Paterson ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 229 KB

Swmnary: The O-silylated enolates of ketones and esters can be phenylthioalkylated by the chlorides ( 2) and (3) under ZnBr2-catalysis; ozonolysis and subsequent sulphoxide thermolysis then gives the corresponding unsaturated 1,5-dicarbonyl compounds.