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Thin-layer spectroelectrochemical study of tetrakis(4-N-methylpyridyl)porphinecobalt(III)

✍ Scribed by Rohrbach, David F.; Deutsch, Edward.; Heineman, William R.; Pasternack, Robert F.

Book ID
127040213
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
402 KB
Volume
16
Category
Article
ISSN
0020-1669

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πŸ“œ SIMILAR VOLUMES

Kinetics of the substitution reaction of
Kinetics of the substitution reaction of thiocyanate with tetrakis(3-N-methylpyridyl)porphinecobalt(III)
✍ George N. Williams; Peter Hambright πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science βš– 151 KB

The equilibrium constant for the first thiocyanate addition to Co(W)tetra(3-N-methylpyridyl)porphine is a factor of two smaller than for the less basic 4-N-methylporphine isomer. This effect is primarily due to a larger Co-SCN dissociation rate constant for the 3-isomer.