The chromatographic behaviour of thirty primary aliphatic amines on Dowex 50 X4 (Na+ and H+), sodium carboxymethylcellulose and Rexyn 102 (Na+) thin layers has been studied using HCl, buffer and salt solutions as eluents. Some interesting separations are reported: the affinity sequences on these exc
Thin-layer chromatographic and electrophoretic behaviour of primary aromatic amines on weak ion exchangers
โ Scribed by D. Cozzi; P.G. Desideri; L. Lepri; V. Coas
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- English
- Weight
- 805 KB
- Volume
- 43
- Category
- Article
- ISSN
- 1873-3778
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โฆ Synopsis
The authors have studied extensively the thin-layer chromatographic and electrophoretic behaviour of primary aromatic amines on weak ion exchangers such as alginic acid and carboxymethylcellulose.
The eluents were solutions of organic and inorganic acids, water, buffer solutions and aqueous organic solvents. The Xr;l values were correlated with the acidity and basicity of many amines.
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๐ SIMILAR VOLUMES
The chromatographic behaviour of 16 metal ions on thin layers of sodium carboxymethylcellulose and Dowex 50-X4 (Na") was investigated. The eluents used were acetate, gluconate, lactate and oxalate buffer solutions at constant ionic strength. The influence on the RI: values of some parameters (the af
The chromatographic behaviour of 58 phenols on thin layers of Bio-Rnd AG 3-X4A, PEI-cellulose and DEAE-cell~dose has been studied with acidic and alkaline solutions, neutral and alkaline alcohol solutions and organic solvent mixtures as eluents. The selectivity of AG 3-X4A layers is ascribed to inte