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Thin-Film Molecular Materials Based on Tetrametallic “Squares”: Nanoscale Porosity and Size-Selective Guest Transport Characteristics

✍ Scribed by Bélanger, Suzanne; Hupp, Joseph T.; Stern, Charlotte L.; Slone, Robert V.; Watson, David F.; Carrell, Thomas G.


Book ID
126246433
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
174 KB
Volume
121
Category
Article
ISSN
0002-7863

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Molecular materials based on thin films of the zinc-containing tetraporphyrinic square assembly, 1, can be rapidly and, in many cases, completely functionalized by exposure to aqueous or alkane solutions of good N-donor ligands such as pyridine and imidazole. Modification can also be achieved via di