✦ LIBER ✦
Thiazolium-ion based organic ionic liquids (OILs).1,2 Novel OILs which promote the benzoin condensation
✍ Scribed by James H. Davis Jr.; Kerri J. Forrester
- Book ID
- 104260823
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 97 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
4-and 5-methyl thiazole are readily alkylalexl with n-butyl bromide followed by anion exchange of Br-for BF 4 to give mobile, room-temperature ionic liquids. These liquids, when treated with small quantities of triethylamine, serve to promote the benzoin condensation of benzaldehyde.