Thiacalix-monocrown ethers with terminal functional groups at the lower rim: Synthesis and structure
✍ Scribed by Solovieva, S. E.; Murav’ev, A. A.; Latypov, Sh. K.; Antipin, I. S.; Konovalov, A. I.
- Book ID
- 110160334
- Publisher
- Springer
- Year
- 2011
- Tongue
- English
- Weight
- 209 KB
- Volume
- 438
- Category
- Article
- ISSN
- 0012-5008
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AbstractÐThe syntheses of pyridyl containing calix [4]arene receptors (4, 5, and 11) that adopt the cone conformation are reported. The complexation properties of these host molecules were estimated via the results of alkali metal picrate extraction experiments. A singlybridged bis-calix[4]arene, i.
Synthetic routes were developed to link L-alanine methyl ester or L-alanyl-L-alanine methyl ester at the upper rim of calix [4]arenes blocked in the cone conformation. Several tetra-(3 and 6) and difunctionalized (11 and 12) amino acids containing macrocycles were obtained. Reaction of these compoun