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TheSaunders-BellAnalysis of Tunnel Effects in Reactions with Kinetic Isotope Effects

✍ Scribed by Vladimir Leskovac; Svetlana Trivić; Draginja Pericčin; Julijan Kandrač

Publisher
Springer Vienna
Year
2004
Tongue
English
Weight
198 KB
Volume
135
Category
Article
ISSN
0026-9247

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✍ Toshitsugu Yokota; Richard B. Timmons 📂 Article 📅 1970 🏛 John Wiley and Sons 🌐 English ⚖ 462 KB 👁 1 views

The competitive reactions of Br atoms with CH, and CD, were studied over the temperature range of 562' to 637°K. Over this temperature interval, the kinetic isotope effect, k,/k,, varied from 3.05 to 2.47 for the reactions Br + CH, -% HBr + CH, The rate constant ratio k,/k, , expressed in Arrhenius