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Thermolytic reactions of esters. Part XIII The effect of electron-attracting α-substituents in alkyl acetates

✍ Scribed by Robert Louw; Arie Tinkelenberg; Erik S. E. Werner


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
375 KB
Volume
102
Category
Article
ISSN
0165-0513

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✍ Nadejda Reikonnen; Ignacio Martin; Gabriel Chuchani; Jacek Lubinkowski 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 314 KB 👁 1 views

## Abstract The gas‐phase eliminations of several __tert__‐butyl esters, in a static system and in vessels seasoned with allyl bromide, have been studied in the temperature range of 171.5–280.1°C and the pressure range of 23–98 torr. The rate coefficients for the homogeneous unimolecular eliminatio