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Thermolysis of the [a.2.2]propellanes. Mechanisms for the thermolysis of bicyclo[2.2.0]hexanes.

โœ Scribed by Kenneth B. Viberg; Micliael G. Mattnrro


Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
230 KB
Volume
22
Category
Article
ISSN
0040-4039

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โœ Albert Padwa; Thomas J. Blacklock; Roman Loza ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 187 KB

The triplet sensitized irradiation of 3-allyl-diaryl-substituted cyclopropenes to m.l.O]hex-2-enes proceeds via an intramolecular [2+2]-cycloaddition followed by a subsequent rearrangement of the initially formed tricycl0[2.2.0.0~~~]hexane skeleton. Previous work from this laboratory has shown that