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Thermolysis of tetra(methyl-d3)-1,2-dioxetane: .beta.-deuterium isotope effect

✍ Scribed by Baumstark, Alfons L.; Vasquez, Pedro C.

Book ID
126028985
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
411 KB
Volume
49
Category
Article
ISSN
0022-3263

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📜 SIMILAR VOLUMES

Thermolysis of 3-alkyl-3-methyl-1,2-diox
Thermolysis of 3-alkyl-3-methyl-1,2-dioxetanes: activation parameters and chemiexcitation yields
✍ Alfons L. Baumstark; Sean L. Anderson; Chariety J. Sapp; Pedro C. Vasquez 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 72 KB

## Abstract 3‐Methyl‐3‐(3‐pentyl)‐1,2‐dioxetane **1** and 3‐methyl‐3‐(2,2‐dimethyl‐1‐propyl)‐1,2‐dioxetane **2** were synthesized in low yield by the α‐bromohydroperoxide method. The activation parameters were determined by the chemiluminescence method (for **1** ΔH‡ = 25.0 ± 0.3 kcal/mol, ΔS‡ = −1

Thermolysis of 3-alkyl-3-methyl-1,2-diox
Thermolysis of 3-alkyl-3-methyl-1,2-dioxetanes: Activation parameters and chemiexcitation yields
✍ Alfons L. Baumstark; Sean L. Anderson; Chariety J. Sapp; Pedro C. Vasquez 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 124 KB

## Abstract 3‐Methyl‐3‐(3‐pentyl)‐1,2‐dioxetane **1** and 3‐methyl‐3‐(2,2‐dimethyl‐1‐propyl)‐1,2‐dioxetane **2** were synthesized in low yield by the α‐bromohydroperoxide method. The activation parameters were determined by the chemiluminescence method (for **1** ΔH‡ = 25.0 ± 0.3 kcal/mol, ΔS‡ = −1