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Thermolysis of oxazolin-5-ones, 12. Formation of a cage compound by thermolysis of 2-(4-Chlorophenyl)-2-(3,3-dimethylallyl)-4-phenyl-5(2H)-oxazolone

✍ Scribed by Fischer, János ;Márványos, Ede ;Párkányi, László ;Kálmán, Alajos ;Steglich, Wolfgang

Publisher
Wiley (John Wiley & Sons)
Year
1988
Tongue
English
Weight
180 KB
Volume
121
Category
Article
ISSN
0009-2940

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✦ Synopsis

During thermolysis of title compound 1, the unusual cage compound 4 is formed (along with 2,3dihydropyridine 3); the structure of 4 was determined by X-ray structure analysis. The formation of 4 can be explained by dimerization of the intermediates 2 and 3.

Thermol ysis of 2-(4-chlorophenyl)-2-(3,3-dimethylallyl)-4-phenyl-

📜 SIMILAR VOLUMES

Synthesis and identification of 2-dimeth
Synthesis and identification of 2-dimethylamino-5-(phenyl-2′-3H)-2-oxazolin-4-one
✍ Charles F. Howell; George Van Lear; Robert A. Hardy Jr. 📂 Article 📅 1970 🏛 John Wiley and Sons 🌐 French ⚖ 254 KB

## Abstract The title compound **1b** was prepared by tritiolysis of 5‐(O‐bromophenyl)‐2‐dimethylamino‐2‐oxazolin‐4‐one, **2**, with 10 Ci of tritium and diluted with unlabelled **1a**. The mass spectrum of the 2′ ‐deutero derivative **1c**, prepared similarly, showed that 92.9 % of labelled compou