๐”– Bobbio Scriptorium
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Thermolysis of benzoyl peroxide in the presence of n-sulphinyl-aniline

โœ Scribed by G. De Luca; G. Renzi; M. Felici; A. Tundo

Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
179 KB
Volume
17
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Recent work assumes the similarity of the electronic and structural characteristics of SO2 and 1-2 N-sulphinyl-aniline . N-alphinyl-anilines(Ar-N=S=O) are heterocumulenes which present a cis3 structure as regards the central bond -N=S; the -N=S=O group is coplanar4 and has a moderate resonance interaction with the benzene ring unless para groups showing conjugative effects and acting as weak r-electron acceptors are present 5-6 . The -N=S is the reactive bond7, as confirmed in our recent research' on the addition of arylnitrenes to double bonds of heteroatoms.

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