Thermolysis of allylic azoalkanes
β Scribed by Engel, Paul S.; Allgren, Robin L.; Chae, Woo-Ki; Leckonby, Roy A.; Marron, Neil A.
- Book ID
- 125982132
- Publisher
- American Chemical Society
- Year
- 1979
- Tongue
- English
- Weight
- 957 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
## Abstract A number of 4βallylic substituted 3,5βdiphenylβ4__H__β1,2,4βtriazoles were thermolyzed at 315β320Β° in evacuated glass ampoules. The main reaction in the melt was rearrangement to the corresponding 1βsubstituted triazoles, which appeared to proceed __via__ competing S~N~2 and S~N~2β² mech
In the course of work designed to explore the synthetic potential of O-ally1 oxime and N-ally1 hydrasone derivatives , we have studied the thermolyses 1 of the oxims O-ally1 ethers 1. =
~wnmazy: Thermolysis of allylic sulfoxides is a useful method for the synthesis of functionalized dienes. Thermal interconversion of allylic sulfoxides and SUlfenateS, eventually followed by nucleophilic decomposition of the latter to alcohols, has found wide application in organic synthe-sis1s2. El