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Thermolysis and [3 + 2]-Cycloaddition Reactions of 2,3-Diferrocenyl- and 2,3-Diruthenocenylcyclopropenones.

✍ Scribed by Elena I. Klimova; Tatiana Klimova Berestneva; Ruben A. Toscano; Jose M. Mendez Stivalet; Marcos Martinez Garcia

Book ID
102001327
Publisher
John Wiley and Sons
Year
2007
Weight
26 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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## Abstract 2,3‐Dimethylene‐2,3‐dihydrothiophene (1), the thiophene analog of o‐xylylene (o‐quinodimethane), was generated __in situ__ from the (trialkylammoniomethyl)‐(trimethylsilylmethyl)thiophene iodides 4 or 5 by fluoride‐induced 1,4 climination, and was trapped by [4 + 2] cycloadditions with