Thermokinetic Studies of Porphyrin Complexation in Non-Aqueous Solutions by Heat Conduction Microcalorimetry
β Scribed by T. Ageeva; E. Utzig; O. Golubchikov; W. Zielenkiewicz
- Book ID
- 110286784
- Publisher
- Springer Netherlands
- Year
- 1998
- Tongue
- English
- Weight
- 320 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0022-5215
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Water-soluble manganese(II1) as well as iron(II1) porphyrinates are introduced as light-sensitive precursor compounds for the photocatalytic activation of dioxygen in aqueous solutions. It is shown that in the presence of a-pinene (4) and the further cycloalkenes 11 -13 photocatalytic oxygenation re