Thermogravimetric analysis of the copper silicate mineral dioptase Cu6[Si6O18]·6H2O
✍ Scribed by Ray L. Frost, Yunfei Xi
- Book ID
- 120744142
- Publisher
- Springer Netherlands
- Year
- 2012
- Tongue
- English
- Weight
- 378 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0022-5215
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The thermal behaviour of dioptase was studied in air, in argon and hydrothermally using X-ray powder diffraction at normal and elevated temperatures, thermal analysis (TGA, DTA), electron microscopy, UV spectrometry and chemical analysis methods. With increasing temperature natural green dioptase tr
The normal modes of vibration and their frequencies are calculated for dioptase, a mineral whose crystal structure (space group R3 or C~i ) consists of puckered six-membered silicate rings (Si6Ols) linked by Cu 2 § ions and HaO groups. The calculation employs a valence force potential consisting of