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Thermodynamics of the primary and secondary photochemical reactions in Chromatium

✍ Scribed by George D. Case; William W. Parson


Book ID
115715736
Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
946 KB
Volume
253
Category
Article
ISSN
0005-2728

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What is Different in Photochemical React
✍ Hartung, Jens ;Hertel, Barbara ;Trach, Frank πŸ“‚ Article πŸ“… 1993 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 537 KB

## Abstract Photochemical cyclization and halogen abstraction reactions of secondary alkylcobaloximes 1b and 1d compared to their primary counterparts 1a and 1c show an enhanced reactivity of secondary alkylcobaloximes: Thus, cyclohexylcobaloxime 1d reacts 13 times faster with CCl~4~ than __n__1‐he