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Thermodynamics of the geometrical isomerization of 2-butene and 2-pentene

โœ Scribed by F. Kapteijn; A.J.van der Steen; J.C. Mol


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
662 KB
Volume
15
Category
Article
ISSN
0021-9614

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H2S-promoted thermal isomerization of ci
โœ D. Perrin; C. Richard; R. Martin ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 457 KB

H,S accelerates the thermal isomerization of cis-2-pentene (P2c) to 1-pentene (P1) and trans-2-pentene (P2t) to around 800 K. This effect is interpreted on the basis of a free radical mechanism in which 2-pentenyl and thiyl radicals are the main chain carriers. P1 formation is essentially explained