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Thermodynamics of tetramethyl + tetramethyl: comparison with theory

✍ Scribed by M.B Ewing; M.L McGlashan


Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
821 KB
Volume
10
Category
Article
ISSN
0021-9614

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## Abstract Arrhenius parameters have been measured for the abstraction of hydrogen from the C Si, Ge, and Sn tetramethyls: The rate constants correlate with the proton chemical shift, which is related to a polar effect. In all cases except carbon, a hot‐molecule β‐fluorine rearrangement‐eliminat