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Thermodynamics of solutions of iodine and perfluorocarbons in cycloalkanes

✍ Scribed by Ian A. McLure; Ahmad Mokhtari

Publisher
Springer US
Year
1982
Tongue
English
Weight
720 KB
Volume
11
Category
Article
ISSN
0095-9782

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First examples of superelectrophile init
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✍ Irena Akhrem; Alexander Orlinkov; Sergei Vitt; Anatolii Chistyakov πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 138 KB

Direct iodination of alkanes and cycloalkanes in the presence of superelectrophiles has been accomplished for the first time. The reactions of saturated hydrocarbons with I 2 in the presence of CCl 4 β€’2AlI 3 at -20Β°C afforded monoiodides in good yields and selectivities.