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Thermodynamics of proton-ligand dissociation of some fluorinated β-diketones in dioxane-water mixtures

✍ Scribed by J.P. Shukla; G.M. Nair; R.S. Sharma


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
784 KB
Volume
149
Category
Article
ISSN
0040-6031

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✍ Turgut Gündüz; Esma Kiliç; Esin Canel; Fitnat Köseo > glu 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 543 KB

Sixteen Schiffs bases have been prepared from sahcylaldehyde and substituted anilines and their stoichiometric protonation constants have been determined in dioxan-water mixtures of 30, 40, 50 and 60% dioxan (v/v) using a combined pH electrode at 25"C, under nitrogen atmosphere. The calculation of t