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Thermodynamics of phenylacetamides synthesis: Linear free energy relationship with the pK of amine

✍ Scribed by Dorel T. Guranda; Gennadij A. Ushakov; Petr G. Yolkin; Vytas K. Švedas

Book ID
113804918
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
521 KB
Volume
74
Category
Article
ISSN
1381-1177

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Dissociation constants (pK a ) of trazodone hydrochloride (TZD ¥ HCl) in EtOH/H 2 O media containing 0, 10, 20, 30, 40, 50, 60, 70, and 80% (v/v) EtOH at 288.15, 298.15, 308.15, and 318.15 K were determined by potentiometric techniques. At any temperature, pK a decreased as the solvent was enriched