Thermodynamics of monomer partitioning in polymer latices: Effect of molar volume of the monomers
β Scribed by Harold A. S. Schoonbrood; Anton L. German
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 236 KB
- Volume
- 15
- Category
- Article
- ISSN
- 1022-1336
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## Abstract A study was made of the effect of carboxylic monomers, such as itaconic acid, acrylic acid, and methacrylic acid, on the relative distribution of acid in the aqueous serum phase to that on the latex surface to that buried in the particle of carboxylated polystyrene latices prepared by e
The e β ects of remaining monomer on hydrolysis of poly(DL-lactide) were examined by adding di β erent amounts of monomer to puriΓed polymer samples. The existence of monomer in the polymerization products was found to enhance hydrolytic degradation of the polymer. A porous texture was observed on the
Ihe pyrociectric properties of the monomer and pztially end fufty polyme~d crystals of the ~~tolu~nc ~lphon3te) of 2,4-hexa&yne-l&diol (TS) were measured along their b axes from tOO to 300 K T-o peaks in the pyroclcctnc current or monomer crystals were found at 192 and 15 1 K. It is concluded that t