Thermodynamics of mixed-gas adsorption
β Scribed by A. L. Myers; J. M. Prausnitz
- Publisher
- American Institute of Chemical Engineers
- Year
- 1965
- Tongue
- English
- Weight
- 760 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0001-1541
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π SIMILAR VOLUMES
A multiregion, extended Langmuir model (MREL) is proposed for predicting multicomponent adsorption equilibria. For a binary mixture, it is assumed that two regions or sites exist on the surfaces. One region or site adsorbs both species from the mixture whereas the other region or site is excluded fr
Based on a modified form of the Gibbs equation, two conditions of thermodynamical correctness have been defined. According to these conditions the change in the free energy of the surface-calculable from all isotherm equations-must have finite limiting values at \(\theta \rightarrow 0\) and \(\theta