𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Thermodynamics of chemical equilibrium — V Multiple-reaction and open systems

✍ Scribed by A.H. Larsen; C.S. Lu; C.J. Pings

Publisher
Elsevier Science
Year
1968
Tongue
English
Weight
598 KB
Volume
23
Category
Article
ISSN
0009-2509

No coin nor oath required. For personal study only.

✦ Synopsis

General thermodynamic expressions are presented for the partial derivatives of the chemical reaction parameter with respect to temperature, pressure, volume, and external composition perturbations for multiple-reaction systems constrained to paths of chemical equilibrium under various conditions. The corresponding heat and temperature effects are given. Derivatives of the chemical reaction parameter are evaluated for ideal solutions. For a closed system involving reactions of methane with steam, values of the derivatives predicted from the thermodynamic analysis agree well with numerical results.

📜 SIMILAR VOLUMES

Diffusion and reaction in ideal multicom
Diffusion and reaction in ideal multicomponent systems: I. Tubular reactor near equilibrium
✍ R. L. Solomon; J. L. Hudson 📂 Article 📅 1971 🏛 American Institute of Chemical Engineers 🌐 English ⚖ 712 KB

## Abstract Diffusion and either surface or gas‐phase reaction in a ternary ideal gas mixture in steady fully developed laminar flow in a tube is considered. The linearized equations valid near equilibrium and under isothermal conditions are solved. Concentration profiles predicted using a multicom

Diffusion and reaction in ideal multicom
Diffusion and reaction in ideal multicomponent systems: II. Behavior away from equilibrium
✍ R. L. Solomon; J. L. Hudson 📂 Article 📅 1971 🏛 American Institute of Chemical Engineers 🌐 English ⚖ 573 KB

## Abstract An analysis is made of diffusion and chemical reaction in an isothermal multicomponent fluid. Transient gas‐phase reaction in a one‐dimensional nonflow system and steady state gas‐phase or surface reaction in a tubular reactor are considered. The equations are linearized around some sta