For alcohol-ahphak hydrocarbon solutions, the athermal assoclakd solut~oon theory of Wlehe and Bagley 1s modlfied by mtroducmg a physical interaction term of the Scatchard-Hfidebrand type expression Good fits between the modlfied theory and experunental data for the excess Gibbs free energy of mlxmg
Thermodynamics of alcohol solutions
✍ Scribed by Isamu Nagata; Kohki Gotoh
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 980 KB
- Volume
- 258
- Category
- Article
- ISSN
- 0040-6031
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📜 SIMILAR VOLUMES
The modlfied Wiehe-Bagley expresslons for GE, He and VE of alcohol-Inert solvent solutions are apphed to alcohol-active solvent solutions Excellent agreement v&h expernnental data IS obtamed, even for HE and VB curves showing a maxunum and mnumum m the composition plots 'l&c alcohol polymerlzatron e
This article critically reconsiders a continuous linear association model based on the work of Flory and Scatchard. The model is used to reduce experimental equilibrium data for solutions of alcohols and saturated hydrocarbons; special attention is given to recent extensive enthalpy data of Van Nes