Addition polymerizations of both acyclic and cyclic monomers show the characteristic features of any aggregation process, in particular, a ceiling temperature above which the formation of the aggregate (long-chain polymer), under given conditions of monomer concentration, solvent, and pressure, woul
Thermodynamics of Addition Polymerization Processes
โ Scribed by Prof. K. J. Ivin
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- English
- Weight
- 667 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0044-8249
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The equilibrium between fluoral in dichloromethane solution and live condensed liquid polyfluoral has been investigated between 22 and 43ยฐC. Equilibrium monomer concentrations gave: AH~cยฐ(298 K) = --50.8 ยฑ 2.3 kJ reel -~ and AS~c ยฐ (298 K) = --142.7 ยฑ 7.4J K -~ mo1-1. With the aid of calibration and