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Thermodynamics of 2,2′,2′'-terpyridinecopper(II) complexes in aqueous solution

✍ Scribed by Rosario Calì; Enrico Rizzarelli; Silvio Sammartano; Giuseppe Siracusa


Book ID
104843217
Publisher
Springer
Year
1979
Tongue
English
Weight
469 KB
Volume
4
Category
Article
ISSN
0340-4285

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Photo-oxidation of tris(2,2'-bipyridine)
✍ Oleg V. Gerasimov; Valentin N. Parmon; Sergei V. Lymar 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 962 KB

Thermal and photochemical oxidations of Fe(bpy)sz+ (bpy=2,2'-bipyridine) by the periodate anion IO,-in acidic aqueous solution were studied. For the thermal process, the rate-limiting step is monomolecular dissociation of the iron(D) complex preceding the fast oxidation by IO,-. Photo-oxidation of F