Thermodynamics and Kinetics of Glyoxal Dimer Formation: A Computational Study
β Scribed by Kua, Jeremy; Hanley, Sean W.; De Haan, David O.
- Book ID
- 120364972
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 220 KB
- Volume
- 112
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
Equilibria and rates of interconversion between monomeric and dimeric glyoxal were measured in aqueous solution. The equilibrium constant [G2]/[GJ2 was 0.56 M-' at 25"C, and was hardly affected by changes of ionic strength and pH but increased rapidly with increase of temperature. The rate of depoly
## Abstract A theoretical study of the properties of the linear LiH dimer was undertaken. In this dimer, an unusual type of hydrogen bonding (termed βinverseβ hydrogen bonding by some authors), which involves the hydrogen bonded molecule acting as an electron donor (rather than as a proton donor),
The reaction of n-butanol with several aromatic diisocyanates -2,4 toluene diisocyanate (2,4 TDI), 2,6 toluene diisocyanate (2,6 TDI), 2,4 0 dibenzyl diisocyanate (2,4 0 DBDI), 4,4 0 stilbene diisocyanate, (4,4 0 SBDI), m-phenylene diisocyanate (m-PDI), and p-phenylene diisocyanate (p-PDI) -resultin